Title of article :
Generation of sulfenylnitrenes by N-sulfenylation of triphenyl-λ6-sulfanenitrile
Author/Authors :
Fujii، نويسنده , , Takayoshi and Kousaka، نويسنده , , Taeko and Yoshimura، نويسنده , , Toshiaki، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
The sulfenylation of triphenyl-λ6-sulfanenitrile (1) with 2,4-dinitrobenzenesulfenyl chloride in the presence of alkenes affords aziridines together with triphenylsulfonium salt. The reaction of 1 with sulfur dichloride also generates ClSN which is trapped by 2,5-diphenylfuran to give 5-benzoylisothiazole.
Keywords :
?6-Sulfanenitrile , sulfenylnitrene , Aziridines , Sulfenylation , thiazyl chloride
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters