• Title of article

    Regioselective and diastereoselective phosphine-catalysed [3+2] cycloadditions to 5-methylenehydantoins: reversal of regioselectivity using chiral N-2-butynoyl-(4S)-benzyloxazolidinone

  • Author/Authors

    Pham، نويسنده , , Tien Q and Pyne، نويسنده , , Stephen G and Skelton، نويسنده , , Brian W and White، نويسنده , , Allan H، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    5953
  • To page
    5956
  • Abstract
    The phosphine-catalysed [3+2] cycloaddition of 5-methylenehydantoins 1 with the ylides 2a and 2b gives spirocyclic products with reverse regioselectivities; the latter ylide gives optically active products.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1653241