Title of article :
The basicity of 1,8-bis(dimethylamino)naphthalene and the hybrid state of the nitrogen atoms of its dimethylamino groups
Author/Authors :
Korzhenevska، نويسنده , , Nadiya G and Rybachenko، نويسنده , , Volodymyr I and Schroeder، نويسنده , , Grzegorz، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
The superbasic properties of 1,8-bis(dimethylamino)naphthalene and its analogues are the result of mainly two factors: violation of conjugation of the dimethylamino group with the π-system of the naphthalene rings and high p-character of the nitrogen lone electron pair.
Keywords :
Amines , proton sponges , Basicity , hybridization
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters