Title of article
Henry condensations with 4,6-O-benzylidenylated and non-protected d-glucose and l-fucose via DBU-catalysis
Author/Authors
Pasit Phiasivongsa، نويسنده , , Pasit and Samoshin، نويسنده , , Vyacheslav V. and Gross، نويسنده , , Paul H.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
5495
To page
5498
Abstract
Mechanistic intermediates, and thermodynamically favored side products, in the Henry condensations of partially protected and non-protected pyranoses with a free anomeric hemiacetal function with nitromethane in various solvents for the kinetically controlled syntheses of C-glycopyranosides in the presence of DBU/molecular sieve catalyst system were identified.
Keywords
Nitromethane , C-glycoside , DBU
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1653578
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