Title of article
Methyltrioxorhenium catalyzed domino epoxidation-nucleophilic ring opening of glycals
Author/Authors
I. Soldaini، نويسنده , , Gianluca and Cardona، نويسنده , , Francesca and Goti، نويسنده , , Andrea، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
5589
To page
5592
Abstract
The use of catalytic methylrhenium trioxide (MTO) and urea hydrogen peroxide in room temperature ionic liquid for the hydroxyglycosylation with glycals in a domino fashion is reported. Excellent conversions and good selectivities for the epoxidation reaction were observed. Application to the synthesis of glycosylphosphates, good glycosyl donors, has been studied.
Keywords
Ionic liquids , Catalysis , glycosyl phosphates , glycosyl donors , Methyltrioxorhenium , Oxidation
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1653599
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