• Title of article

    LiBF4: a mild and novel reagent for the OH insertion reactions of α-diazoketones

  • Author/Authors

    Yadav، نويسنده , , J.S. and Reddy، نويسنده , , B.V.S. and Vishnumurthy، نويسنده , , P.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    5691
  • To page
    5694
  • Abstract
    Lithium tetrafluoroborate (10 mol%) is found to catalyze efficiently the OH insertion reactions of α-diazoketones with various alcohols including benzylic, allylic, propargylic and cyclopropyl carbinols to produce the corresponding α-alkoxy ketones in excellent yields with high selectivity. A solution of 10 mol% of LiBF4 in acetonitrile provides a convenient reaction medium to carry out the OH insertion reactions under mild and neutral conditions.
  • Keywords
    Lithium salts , Insertion reactions , ?-alkoxy ketones , ?-diazoketones
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1653648

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1653648