Author/Authors :
Iqbal، نويسنده , , Mazhar and Evans، نويسنده , , Paul، نويسنده ,
Abstract :
The synthesis of 5-alkylidenecyclopent-2-enones is readily achieved in two steps via a one-pot conjugate addition–Peterson olefination sequence, using exo-2-trimethylsilyl-3a,4,7,7a-tetrahydro-4,7-methanoinden-1-one, followed by a retro-Diels–Alder reaction.