Title of article :
A new family of delocalized lipophilic cations
Author/Authors :
Henrich، نويسنده , , Marielouise and Marhold، نويسنده , , Albrecht and Kolomeitsev، نويسنده , , Alexander A and Kalinovich، نويسنده , , Natalya and Rِschenthaler، نويسنده , , Gerd-Volker، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
A new family of delocalized lipophilic cations containing one to three carbimino, sulfimino and phosphinimino units with Cl−, Br−, HF2− and Me3SiF2− as counterions has been designed. The compounds synthesized demonstrate high performance and thermal stability in the ‘Halex’ fluorination reactions. For the first time sulfur tetrachloride pregenerated at −78°C was successfully applied in reactions with N-nucleophiles to afford straightforwardly sulfonium chlorides with three S–N bonds.
Keywords :
Delocalized lipophilic cations , halogen exchange fluorination , aminosulfonium salts
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
