• Title of article

    CC bond formation using allylic organozirconium compounds. Nucleophilic additions on to isolated and in situ generated η5-pentadienyl-Fe(CO)3/Fe(CO)2PPh3(+1) cations

  • Author/Authors

    Motiei، نويسنده , , Leila and Marek، نويسنده , , Ilan and Gottlieb، نويسنده , , Hugo E and Marks، نويسنده , , Vered and Lellouche، نويسنده , , Jean-Paul، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    5909
  • To page
    5912
  • Abstract
    Two nucleophilic allylic organozirconium compounds 9–10 (R5: Me and tBu) have been reacted with acyclic isolated η5-pentadienyl-Fe(CO)3/Fe(CO)2PPh3(+1) cations or with these intermediates generated in situ (Uemura-like conditions). Depending on reaction conditions, iron-complexed η4-dienyl-Fe(CO)3/Fe(CO)2PPh3 and σ,η3-π-allyl-Fe(CO)3/Fe(CO)2PPh3 condensation products have been selectively isolated and fully characterized.
  • Keywords
    organozirconium compounds , (?5-pentadienyl)Fe(CO)3/Fe(CO)2PPh3(+1) cations , carbon?carbon bond formation
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1653752

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1653752