Title of article :
A new method for the preparation of fluoro-λ6-sulfanenitriles: reaction of sulfimides with Selectfluor™
Author/Authors :
Fujii، نويسنده , , Takayoshi and Asai، نويسنده , , Shinsuke and Okada، نويسنده , , Tomoyuki and Hao، نويسنده , , Wei and Morita، نويسنده , , Hiroyuki and Yoshimura، نويسنده , , Toshiaki، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Several diaryl(fluoro)-λ6-sulfanenitriles 3 were synthesized by the reaction of S,S-diarylsulfimides 1 with Selectfluor™. This reaction also allows the first preparation of heterocyclic fluoro-λ6-sulfanenitrile, 5-fluoro-10,10-dioxo-5,10-dihydro-5λ6,10λ6-thianthren-5-nitrile (5) and its molecular structure was determined by X-ray crystallographic analysis.
Keywords :
sulfimides , Selectfluor™ , fluorination , Heterocycles , X-ray crystallographic analysis , fluoro-?6-sulfanenitriles
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
