Title of article
β-Sulfinyl acrylate esters as a convenient source of alkane- and arenesulfenate anions
Author/Authors
OʹDonnell، نويسنده , , Jennifer S. and Schwan، نويسنده , , Adrian L.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
6293
To page
6296
Abstract
Methyl acrylate esters bearing alkane- and arenesulfinyl units on the 2-carbon liberate sulfenate anions upon nucleophilic attack. The sulfenates are readily captured through sulfur alkylation. When a sulfenate derived from R-cysteine is generated, diastereoselective benzylation is observed.
Keywords
Alkylation , Sulfoxide , sulfinylcysteine , sulfenate
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1653963
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