Title of article
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates
Author/Authors
Romashin، نويسنده , , Yuri N and Liu، نويسنده , , Michael T.H and Hill، نويسنده , , Brian T and Platz، نويسنده , , Matthew S، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
6519
To page
6521
Abstract
Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide involves the formation of a sulfur ylide intermediate, followed by H-migration, 2,3-sigmatropic shift, or ring opening to give sulfides. The sulfur ylide formed in the reaction of phenylcarbene with trimethylenesulfide is directly observed by laser flash photolytic techniques.
Keywords
Diazirine , Carbene , adamantylidene , Kinetics , Sulfur ylide , Laser flash photolysis , trimethylenesulfide
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654129
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