Title of article
Stereoselective cycloaddition of 1-glucosyl-1,3-butadienes with tert-butyl 2H-azirine-3-carboxylate, glyoxylates and imines
Author/Authors
Alves، نويسنده , , M.José and Almeida، نويسنده , , I.G. and Gil Fortes، نويسنده , , A. and Freitas، نويسنده , , A.P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
6561
To page
6565
Abstract
Glucosyl dienes 1 have been reacted with the achiral 2H-azirine 4 and with glyoxylates, forming fused structures of type 5 and disaccharide-like compounds 7 with good to excellent selectivity. Glucosyl dienes 1 participated as dienophiles in reactions with Schiff bases derived from anilines forming isoquinolines 10 and 11. The diastereoselectivity of this reaction is poor.
Keywords
cycloaddition , 1 , 3-butadienes , glyoxylates , 2H-azirines , imines
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654153
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