• Title of article

    A novel redox switch for fluorescence: drastic UV–vis and fluorescence spectral changes upon electrolysis of a hexaphenylethane derivative of 10,10′-dimethylbiacridan

  • Author/Authors

    Suzuki، نويسنده , , Takanori and Migita، نويسنده , , Akira and Higuchi، نويسنده , , Hiroki and Kawai، نويسنده , , Hidetoshi and Fujiwara، نويسنده , , Kenshu and Tsuji، نويسنده , , Takashi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    6837
  • To page
    6840
  • Abstract
    The newly prepared title donor 1 has a very long CC bond [1.635(2) Å], which was readily cleaved upon oxidation to give dication 22+ containing two 10-methylacridinium chromophores. Colorless donor 1 (Eox +0.18 V) is non-fluorescent whereas orange dication 22+ (Ered −0.27 V) emits strong green fluorescence, so that, this pair can be considered as a novel redox switch for fluorescence with high electrochemical bistability.
  • Keywords
    Dication , fluorescence , electrochromism , Electron donor , biacridan , Redox switch , acridinium
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1654364

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1654364