Title of article :
Selective functionalisation of hydrocarbons by nitric acid and aerobic oxidation catalysed by N-hydroxyphthalimide and iodine under mild conditions
Author/Authors :
Minisci، نويسنده , , Francesco and Recupero، نويسنده , , Francesco and Gambarotti، نويسنده , , Cristian and Punta، نويسنده , , Carlo and Paganelli، نويسنده , , Roberto، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
Alkylbenzenes are selectively functionalised to the corresponding acetates by nitric aerobic oxidation catalysed by N-hydroxyphthalimide and iodine. With cyclohexane the oxidation leads to a mixture of cyclohexyl acetate and trans-2-iodocyclohexyl acetate. The mechanism is discussed.
Keywords :
Oxygen , N-hydroxyphthalimide , Alkylaromatics , Acetoxylation , Functionalisation , iodine , Cyclohexane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
