Title of article
Stereoselective oxidation of thiacalix[4]arenes with the NaNO3/CF3COOH system
Author/Authors
Lhot?k، نويسنده , , Pavel and Mor?vek، نويسنده , , Ji??́ and ?mejkal، نويسنده , , Tom?? and Stibor، نويسنده , , Ivan and Sykora، نويسنده , , Jan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
7333
To page
7336
Abstract
A series of alkyl substituted thiacalix[4]arene derivatives (being conformationally mobile or immobilised in the cone conformation) was used as the starting point for this study. It was demonstrated that the NaNO3/CF3COOH system can serve as an excellent oxidising agent. The oxidation of the bridging sulphur atoms smoothly leads to the corresponding tetrasulfoxides where alkyl and sulfoxide groups are oriented in the opposite directions in a stereoselective manner.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654758
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