The first enantiospecific synthesis of (−)-koumidine via the intramolecular palladium-catalyzed enolate driven cross coupling reaction. The stereospecific introduction of the 19-(Z) ethylidene side chain
Author/Authors :
Cao، نويسنده , , Hui and Yu، نويسنده , , Jianming and Wearing، نويسنده , , Xiangyu Z. and Zhang، نويسنده , , Chunchun and Liu، نويسنده , , Xiaoxiang and Deschamps، نويسنده , , Jeffery and Cook، نويسنده , , James M.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Pages :
5
From page :
8013
To page :
8017
Abstract :
The stereospecific synthesis of (−)-koumidine was realized by replacement of triphenylphosphine with tricyclohexylphosphine in the enolate driven palladium-catalyzed cross coupling process.