• Title of article

    Water-mediated transition-metal-free Tsuji–Trost-type reaction

  • Author/Authors

    Chevrin، نويسنده , , Carole and Le Bras، نويسنده , , Jean and Hénin، نويسنده , , Françoise and Muzart، نويسنده , , Jacques، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    8099
  • To page
    8102
  • Abstract
    The treatment of 1-acetoxy-1,3-diphenylpropene (1) by C-, O-, S- and N-nucleophiles in basic aqueous media produced the corresponding substitution products in the absence of a transition-metal catalyst. Mechanistic studies, using (S)-1 and p-MeC6H4CH(OAc)CHCHPh as substrates, led to propose a BAL1 cleavage of the ester function leading to a stabilized allylic carbocation as intermediate.
  • Keywords
    allylic acetate , water chemistry , Substitution , BAL1-SN1? mechanism , PALLADIUM
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1655263

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1655263