Title of article
A highly selective photoinduced selenoperfluoroalkylation of terminal acetylenes by using a novel binary system of perfluoroalkyl iodide and diphenyl diselenide
Author/Authors
Tsuchii، نويسنده , , Kaname and Ogawa، نويسنده , , Akiya، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
8777
To page
8780
Abstract
Upon irradiation through Pyrex with a xenon lamp (hν>300 nm), terminal acetylenes undergo highly selective selenoperfluoroalkylation with perfluoroalkyl iodide and diphenyl diselenide. In this reaction, perfluoroalkyl and phenylseleno groups are selectively introduced into the terminal and internal positions of acetylenes, respectively.
Keywords
high regioselectivity , Diselenide , Photoinitiation , radical reactions , Perfluoroalkyl iodide , Alkynes , high stereoselectivity
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1655733
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