Title of article :
CH3ReO3/H2O2 in room temperature ionic liquids: an homogeneous recyclable catalytic system for the Baeyer–Villiger reaction
Author/Authors :
Bernini، نويسنده , , Roberta and Coratti، نويسنده , , Antonietta and Fabrizi، نويسنده , , Giancarlo and Goggiamani، نويسنده , , Antonella، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2003
Abstract :
The Baeyer–Villiger oxidation of cyclic ketones can be effected by methyltrioxorhenium/hydrogen peroxide in the ionic liquid [bmim]BF4. After simple extraction of the lactone with diethyl ether, the catalyst can be repeatedly recycled and efficiently reused for the lactonisation process in the same reaction medium.
Keywords :
Ionic liquids , Lactones , cyclic ketones , Baeyer–Villiger reaction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters