Title of article :
Selective transformation of ascomycin into 11-epi-ascomycin
Author/Authors :
Baumann، نويسنده , , Karl and Bacher، نويسنده , , Markus and Damont، نويسنده , , Annelaure and Steck، نويسنده , , Andrea، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Within the binding domain, ascomycin features the unusual pattern of a masked tricarbonyl moiety, which potentially allows for high structural diversity via simple isomerisation events. A cascade of diastereoselective rearrangement reactions at the binding domain, allowing the conversion of ascomycin into 11-epi-ascomycin is herein reported.
Keywords :
Tricarbonyl , binding domain , Epimerisation , Rearrangement , Ascomycin
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
