Title of article :
Asymmetric synthesis of γ-perfluoroalkyl(aryl) butyrolactones via organoboranes
Author/Authors :
Ramachandran، نويسنده , , P.Veeraraghavan and Padiya، نويسنده , , Kamlesh J. and Rauniyar، نويسنده , , Vivek Y. Reddy، نويسنده , , M.Venkat Ram and Brown، نويسنده , , Herbert C.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Asymmetric ‘allyl’boration of fluorinated aldehydes with α-pinene-based ‘allyl’ boranes provides the corresponding homoallylic alcohols in high ee and de, which upon hydroboration, followed by oxidation with TPAP/NMO furnish γ-perfluoroalkyl(aryl)-γ-butyrolactones.
Keywords :
Allylboration , ?-pinene , Homoallylic alcohol , Fluorolactones , Hydroboration
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
