Title of article :
Cyclization of dienols, polyenes, and dienyne mediated by mercuric salts: course of cyclizations controlled by stability of cationic intermediates
Author/Authors :
Takao، نويسنده , , Hiroko and Wakabayashi، نويسنده , , Akihito and Takahashi، نويسنده , , Kazuya and Imagawa، نويسنده , , Hiroshi and Sugihara، نويسنده , , Takumichi and Nishizawa، نويسنده , , Mugio Nishizawa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Course of cyclization of dienols, polyenes, and dienyne mediated by mercuric salts were controlled by stability of cationic intermediates and source of mercuric salts. Reaction of (E)-5,9-dimethyl-4,8-decadiene-1-ol with mercuric acetate gave the intramolecular oxymercuration product, whereas one with mercuric triflate produced the olefin cyclization products.
Keywords :
cyclization , Mercury and compounds
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
