Title of article :
Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes
Author/Authors :
Nii، نويسنده , , Shinsuke and Terao، نويسنده , , Jun and Kambe، نويسنده , , Nobuaki، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at −20 °C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed.
Keywords :
Titanocene dichloride , allyl ether , Allylsilane , Grignard reagent , Chlorosilane
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
