Title of article :
Unprecedented chemo-enzymatic synthesis of stereochemically pure 3-acetoxy-2-methyl-2-vinylcycloalkanones
Author/Authors :
Ken-ichi Fuhshuku، نويسنده , , Ken-ichi and Tomita، نويسنده , , Mina and Sugai، نويسنده , , Takeshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
A new approach to 3-acetoxy-2-methyl-2-vinylcyclohexanone and 3-acetoxy-2-methyl-2-vinylcyclopentanone in stereochemically pure state, by means of a combination of yeast-catalyzed reduction and subsequent radical β-fragmentation is described.
Keywords :
Substituted cyclohexanone , Substituted cyclopentanone , Hydroxyketone , Radical ?-fragmentation
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
