Title of article
Ti(III)-catalyzed radical cyclization of 6,7-epoxygeranyl acetate
Author/Authors
Fuse، نويسنده , , Shinichiro and Hanochi، نويسنده , , Malcoln and Doi، نويسنده , , Takayuki and Takahashi، نويسنده , , Takashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
1961
To page
1963
Abstract
The reductive cyclization of epoxygeranyl acetate (1) was investigated using a catalytic amount of Cp2TiCl with various additives. The newly developed Cp2TiCl–Mn–lutidine · HCl–BEt3 system was found to be as effective as the reported stoichiometric system to afford the cyclized dehydro products 4 and 5 with 72% selectivity.
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657359
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