Author/Authors :
Sartori، نويسنده , , Sabrina and Qi، نويسنده , , Xiumei and Eigen، نويسنده , , Nico and Muller، نويسنده , , Jiri and Klassen، نويسنده , , Thomas and Dornheim، نويسنده , , Martin and Hauback، نويسنده , , Bjّrn C.، نويسنده ,
Abstract :
In this work Mg- and K-containing alanates have been investigated as possible hydrogen storage materials. Ball milling was carried out under argon or at moderate/high hydrogen pressure in order to obtain an improved driving force for the formation of potential new alanate phases. Powder X-ray diffraction and volumetric measurements were used in order to identify reaction mechanisms and phases forming in these systems. New unidentified peaks were detected for the mixtures 2MgH2 + 3Al + KH and 2CaH2 + Al + 2KH. However, they do not seem to belong to reversible hydride phases.
