• Title of article

    Regio- and stereochemistry of inter- and intramolecular titanium-mediated coupling of imides and mono-substituted olefins

  • Author/Authors

    Kim، نويسنده , , Se-Ho and Park، نويسنده , , Yongyoub and Choo، نويسنده , , Hyunah and Cha، نويسنده , , Jin Kun، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    6657
  • To page
    6660
  • Abstract
    The intramolecular titanium-mediated coupling reaction of α-substituted succinimides and mono-substituted olefins took place with complete regiocontrol, but without diastereoselectivity. The corresponding intermolecular coupling exhibited lack of regio- and diastereocontrol. Also included were stereochemical studies of catalytic hydrogenation and NaBH3CN reduction of the cyclization products.
  • Keywords
    Pyrrolizidine alkaloids , N-acylhemiaminals , Titanium , succinimides
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1658016