Title of article
Regio- and stereochemistry of inter- and intramolecular titanium-mediated coupling of imides and mono-substituted olefins
Author/Authors
Kim، نويسنده , , Se-Ho and Park، نويسنده , , Yongyoub and Choo، نويسنده , , Hyunah and Cha، نويسنده , , Jin Kun، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
6657
To page
6660
Abstract
The intramolecular titanium-mediated coupling reaction of α-substituted succinimides and mono-substituted olefins took place with complete regiocontrol, but without diastereoselectivity. The corresponding intermolecular coupling exhibited lack of regio- and diastereocontrol. Also included were stereochemical studies of catalytic hydrogenation and NaBH3CN reduction of the cyclization products.
Keywords
Pyrrolizidine alkaloids , N-acylhemiaminals , Titanium , succinimides
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1658016
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