• Title of article

    Reducing oligosaccharides via glycal assembly: on the remarkable stability of anomeric hydroxyl groups to global deprotection with sodium in liquid ammonia

  • Author/Authors

    Iserloh، نويسنده , , Ulrich and Dudkin، نويسنده , , Vadim and Wang، نويسنده , , Zhi-Guang and Danishefsky، نويسنده , , Samuel J، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    7027
  • To page
    7030
  • Abstract
    Several partially benzylated 1-hydroxy sugars were rapidly deprotected by sodium/liquid ammonia. The terminal hemiketal linkage of the substrates remained intact under these conditions and does not generate ring-opened alditols. Peracetylated glucose and glucosamine derivatives were obtained in 64–79% isolated yields.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1658219