Title of article
Synthesis of constrained cycloalkyl analogues of glutamic acid with an ω-phosphonic acid function
Author/Authors
Bessières، نويسنده , , Bernard and Schoenfelder، نويسنده , , Angèle and Verrat، نويسنده , , Céline and Mann، نويسنده , , André and Ornstein، نويسنده , , Paul and Pedregal، نويسنده , , Conception، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
7659
To page
7662
Abstract
A general method based on the sequential reactivities of bis-bromocycloalkenes (3–5) is proposed for the preparation of phosphonocycloalkanes (1a/b–3a/b), representing structural constrained analogues of AP4. For the synthesis of an additional congested AP4 analogue (4), an intramolecular cyclopropanation of a ketocarbene towards a vinyphoshonate, assisted by Rh(OAc)2 was successfully experimented.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1658599
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