Author/Authors :
Ding، نويسنده , , Rui and Ge، نويسنده , , Cheng-Sheng and Chen، نويسنده , , Yongjun and Wang، نويسنده , , Dong and Li، نويسنده , , Chao-Jun، نويسنده ,
Abstract :
In the presence of a rhodium catalyst, a chiral glyoxylate hydrate reacts with arylbismuth and aryllead reagents in water and under an atmosphere of air to give the corresponding addition products in high yields. The diastereoselectivities of the reactions were dramatically improved by using water as the solvent.