Title of article
Koch carbonylation using silver trifluoromethanesulfonate
Author/Authors
Mori، نويسنده , , Hajime and Mori، نويسنده , , Aya and Xu، نويسنده , , Qiang and Souma، نويسنده , , Yoshie، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
7871
To page
7874
Abstract
Koch carbonylation was carried out using silver trifluoromethanesulfonate (AgOTf). Tertiary alcohols were transformed into the corresponding carboxylic acids in good yield under carbon monoxide atmosphere (5 MPa: initial pressure) at 150°C. It can be assumed that under these reaction conditions, a strong acid, in which a silver(I) cation participates, would be generated from AgOTf.
Keywords
tert-carboxylic acid , Koch reaction , silver trifluoromethanesulfonate
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1658736
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