Author/Authors :
Takacs، نويسنده , , James M. and Vayalakkada، نويسنده , , Suresh and Mehrman، نويسنده , , Steven J. and Kingsbury، نويسنده , , Celia L.، نويسنده ,
Abstract :
The first total synthesis of (−)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.
