Author/Authors :
Hogan، نويسنده , , Gregg A and Gallo، نويسنده , , August A and Nicholas، نويسنده , , Kenneth M and Srivastava، نويسنده , , Radhey S، نويسنده ,
Abstract :
The copper(I) complex [Cu(CH3CN)4]PF6 catalyzes the allylic amination of alkenes by aryl hydroxylamine in fair to moderate yields. Unsymmetrical alkenes react with high regioselectivity with N-functionalization occuring at the less substituted vinylic carbon. Trapping experiments indicate that free PhNO is not an intermediate in these reactions.
