• Title of article

    Development of new asymmetric two-center catalysts in phase-transfer reactions

  • Author/Authors

    Tomoyuki Shibuguchi، نويسنده , , Tomoyuki and Fukuta، نويسنده , , Yuhei and Akachi، نويسنده , , Yoko and Sekine، نويسنده , , Akihiro and Ohshima، نويسنده , , Takashi and Shibasaki، نويسنده , , Masakatsu، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    5
  • From page
    9539
  • To page
    9543
  • Abstract
    A new asymmetric two-center phase-transfer catalyst was designed and a catalyst library containing more than 40 new two-center catalysts was constructed. The catalysts were applied in phase-transfer alkylations and Michael additions to afford the corresponding products in up to 93% ee and 82% ee, respectively.
  • Keywords
    Alkylation , asymmetric two-center catalyst , Phase-transfer catalysis , Michael addition
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1659705