Title of article
Novel entry into oxepane–diquinane and oxepane–sterpurane hybrids: synthesis and photochemistry of 3-oxatricyclo[7.2.2.01,7]tridecenones
Author/Authors
Singh، نويسنده , , Vishwakarma and Vedantham، نويسنده , , Punitha and Kane، نويسنده , , Vinayak V and Polborn، نويسنده , , Kurt، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
475
To page
478
Abstract
A new synthesis of 3-oxatricyclo[7.2.2.01,7]tridecenones via intramolecular π4s+π2s cycloaddition in cyclohexa-2,4-dienones is described. Their photochemical reactions leading to oxepane–diquinane and oxepane–sterpurane hybrids are depicted. The crystal structure of a key intermediate is also presented.
Keywords
intramolecular cycloaddition , oxa-di-?-methane rearrangement , photoreactions
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660092
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