Title of article
Synthetic studies on the dienophile unit of methyl isosartortuoate. Part 2: SmI2-mediated 14-membered carbocyclization
Author/Authors
Hong، نويسنده , , Zhangyong and Xu، نويسنده , , Xingxiang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
489
To page
491
Abstract
The dienophile unit of methyl isosartortuoate has been synthesized. The 14-membered carbocycle was constructed by a SmI2-mediated intramolecular Reformatsky reaction. The introduction of the oxo group at the γ-position of the α,β-unsaturated ester was achieved by rearrangement of an β,γ-epoxy ester.
Keywords
dienophile unit , ?-epoxy ester rearrangement , ? , Carbocyclization , SmI2-mediated , methyl isosartortuoate
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660098
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