Title of article
Synthesis of 2,3-diaminodihydropyrroles via thioimidate cyclopropane rearrangement
Author/Authors
Kuduk، نويسنده , , Scott D and Ng، نويسنده , , Christina L. Chang، نويسنده , , Ronald K and Bock، نويسنده , , Mark G، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
1437
To page
1440
Abstract
The synthesis of novel 2,3-diaminodihydropyrroles is reported. The key step is a thiomethylimidate cyclopropane rearrangement to afford a pyrrolothiomethylimidate intermediate. Reaction of this intermediate with amines produced the title compounds in good yields. The scope and mechanism of the reaction is discussed.
Keywords
Cyclopropane , Imidate , dihydropyrroles , Rearrangement
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660642
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