Title of article
Reactions of the carbanion of chloromethyl methyl sulfone with aldehydes and ketones
Author/Authors
Mieczys law Makosza، نويسنده , , Mieczys?aw and Urba?ska، نويسنده , , Natalia and Chesnokov، نويسنده , , Alexey A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
1473
To page
1475
Abstract
Addition of the carbanion of chloromethyl methyl sulfone to aldehydes and ketones proceeds faster than its degradation via the Ramberg–Baecklund reaction. Chlorohydrins and oxiranes produced from aldehydes treated with an excess of base undergo the Ramberg–Baecklund reaction giving allylic alcohols, whereas the reaction of ketones gives the oxiranes.
Keywords
Ramberg–Baecklund reaction , Allylic alcohols , carbanions , chloromethyl methyl sulfone
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660665
Link To Document