Author/Authors :
Lee، نويسنده , , En-Kyung and Kim، نويسنده , , Sang-Han and Jung، نويسنده , , B.-H. and Ahn، نويسنده , , Wha-Seung and Kim، نويسنده , , Geon-Joong، نويسنده ,
Abstract :
Chiral imidazolidine ligands have been synthesized from N,N′-dialkylated cyclohexanediamine derivatives and they were found to act as effective ligands in the palladium-catalyzed asymmetric allylic substitution. The excellent levels of enantiomeric excess up to 98% were obtained in high yield.