Title of article
On the construction of 2-substituted 1,4-diacetoxybutadiene moiety: application to the synthesis of (±)-caulerpenyne
Author/Authors
Laurent Commeiras، نويسنده , , Laurent and Santelli، نويسنده , , Maurice and Parrain، نويسنده , , Jean-Luc، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
2311
To page
2314
Abstract
The synthesis of 2-substituted 1,4-diacetoxybutadiene derivatives with a partial control of stereochemistry is described from two potentially precursor enals by a judicious choice of experimental conditions (Ac2O/DMAP in Et3N). These conditions have been successfully applied in the first total synthesis of caulerpenyne.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1661166
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