Title of article
Short, stereoselective synthesis of C-glycosyl asparagines via an olefin cross-metathesis
Author/Authors
Nolen، نويسنده , , Ernest G and Kurish، نويسنده , , Adam J and Wong، نويسنده , , Kelli A and Orlando، نويسنده , , Michael D، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
2449
To page
2453
Abstract
The Grubbs second generation ruthenium catalyst was employed for the cross metathesis between α- and β-C-allyl glycosides and suitably protected l-vinyl glycines to furnish olefinic products in 57–94% yields. Hydrogenation afforded the C-glycosyl asparagines in high yield.
Keywords
C-glycosyl amino acid , vinyl glycines , C-glycosyl asparagine , C-Allyl glycoside , cross-metathesis
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1661262
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