Title of article
A general protocol for the regio high yielding opening of different glycidol derivatives
Author/Authors
Bonini، نويسنده , , Carlo and Chiummiento، نويسنده , , Lucia and Lopardo، نويسنده , , Maria Teresa and Pullez، نويسنده , , Maddalena and Colobert، نويسنده , , Françoise and Solladié، نويسنده , , Guy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
2695
To page
2697
Abstract
Differently protected glycidol derivatives (with Bn, TBDPS, TBS and MPM groups) have been tested for regioselective ring opening with vinylmagnesium bromide in order to obtain useful five-carbon functionalised homoallylic alcohols. Careful choice of the reagents and experimental conditions allowed a general access to important chiral synthons for asymmetric synthesis.
Keywords
Glycidol , vinylmagnesium bromide , Cuprate , Ring opening
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1661423
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