Author/Authors :
McGarvey، نويسنده , , Glenn J. and Schmidtmann، نويسنده , , Frank W. and Benedum، نويسنده , , Tyler E. and Kizer، نويسنده , , Darin E. Jones، نويسنده ,
Abstract :
As part of efforts to make available new classes of bioactive C-glycoconjugates, d-glucosamine has been effectively converted into a series of 2-deoxy-2-amino-C-glycosides. This versatile approach is keyed by a remarkably effective metal catalyzed olefin isomerization of the isomeric C-allyl amino sugars which, in turn, are readily available via radical allylation of d-glucosamine.
