Author/Authors :
Das، نويسنده , , Subhabrata and Bhowmick، نويسنده , , Tandra and Punniyamurthy، نويسنده , , T. and Dey، نويسنده , , Deepa and Nath، نويسنده , , Jayashree and Chaudhuri، نويسنده , , Mihir K.، نويسنده ,
Abstract :
The molybdenum(VI) peroxo complex 1, synthesized from the reaction of MoO3 with H2O2 and 3,5-dimethylpyrazole (dmpz), selectively oxidizes benzylic C-H bonds of alkylbenzenes to the corresponding alcohols and ketones in moderate to good yields in the presence of H2O2 in acetonitrile under reflux (ca. 80°C).
Keywords :
alkylbenzene , Selective oxidation , molybdenum peroxo complex , Hydrogen peroxide
