Title of article
Electrochemical asymmetric epoxidation of olefins by using an optically active Mn-salen complex
Author/Authors
Tanaka، نويسنده , , Hideo and Kuroboshi، نويسنده , , Manabu and Takeda، نويسنده , , Hironori and Kanda، نويسنده , , Hisaaki and Torii، نويسنده , , Sigeni، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
7
From page
75
To page
81
Abstract
Enantioselective electro-epoxidation of olefins by using an optically active Mn-salen complex, (S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (3), as a mediator in a CH2Cl2 aqueous NaCl two-phase system was performed successfully in a simple undivided cell under constant current conditions. Optimization of the electrolysis conditions and estimation of the reaction mechanism are discussed.
Keywords
epoxidation , Manganese compounds , electrochemical reaction , alkenes , Asymmetric induction
Journal title
Journal of Electroanalytical Chemistry
Serial Year
2001
Journal title
Journal of Electroanalytical Chemistry
Record number
1664529
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