Title of article
An analysis of the containment of electrochemically generated unstable radicals in cylindrical cells
Author/Authors
Kwangsin Kim and Thomas Z. Fahidy، نويسنده , , Thomas Z. and Sioda، نويسنده , , Roman E.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
7
From page
95
To page
101
Abstract
Time variant and steady state concentration profiles of electrochemically generated unstable radical ions in cylindrical cells are analysed in various electrode/cell geometry configurations. The effect of diffusion and mass transport at the cell periphery is discussed, and numerical illustrations using the decomposition of 9-substituted 10-phenylanthracene cation radicals are provided. The choice of configuration is determined by the extent of desired radical containment.
Keywords
electrodes , Phenylanthracene cation radicals , Cell geometry , decomposition
Journal title
Journal of Electroanalytical Chemistry
Serial Year
2000
Journal title
Journal of Electroanalytical Chemistry
Record number
1667163
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