Author/Authors :
Bergamini، نويسنده , , J.F. and Delaunay، نويسنده , , J. and Hapiot، نويسنده , , P. and Hillebrand، نويسنده , , M. and Lagrost، نويسنده , , C. and Simonet، نويسنده , , J. and Volanschi، نويسنده , , E.، نويسنده ,
Abstract :
The cathodic cyclodimerization reaction of two vinylarylsulfones was investigated using cyclic voltammetry and UV-spectroelectrochemical techniques. The results indicate an E→CE← sequence, where the chemical step is a dimerization anion radical–substrate. The proposed mechanism involved a catalytic cycle (ETC), based on the facts that (i) the reduction potential of the dimer is more negative than that of the monomer; (ii) cleavage rates of sulfone anion-radicals are slower than electron exchange rates. AM1-modeling of the reaction routes implying the anion radical–substrate dimerization that leads to the dimer anion radical supports the proposed reaction mechanism.
