Title of article
Hydrogen storage in dinuclear Pt(II) metallacycles
Author/Authors
Kombarakkaran، نويسنده , , Justine and Noveron، نويسنده , , Juan C. and Helgesen، نويسنده , , Michael and Shen، نويسنده , , Kai and Pietraك، نويسنده , , Tanja، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
6
From page
5704
To page
5709
Abstract
Hydrogen gas physisorption in two distinct dinuclear Pt(II) metallacycles was investigated with 2H nuclear magnetic resonance (NMR) spectroscopy. Hydrogen adsorption isotherm data and 2H NMR spectroscopy indicated that hydrogen storage occurs via condensation within the cavities of one of the macrocycles and at the interstitial sites in the other. In addition, this study further supports the notion that heat of adsorption and pore size play critical roles in hydrogen storage.
Keywords
Hydrogen storage , NMR , Platinum metallacycles
Journal title
International Journal of Hydrogen Energy
Serial Year
2009
Journal title
International Journal of Hydrogen Energy
Record number
1674869
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