Title of article
Voltammetry at porous electrodes: A theoretical study
Author/Authors
Barnes، نويسنده , , Edward O. and Chen، نويسنده , , Xiaojun and Li، نويسنده , , Peilin and Compton، نويسنده , , Richard G.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
9
From page
92
To page
100
Abstract
Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface.
Keywords
Templated porous electrodes , Cyclic voltammetry , Potential step chronoamperometry , Diffusion within a sphere
Journal title
Journal of Electroanalytical Chemistry
Serial Year
2014
Journal title
Journal of Electroanalytical Chemistry
Record number
1678157
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